Instantaneous global ozone balance including observed nitrogen dioxide     

Susan Solomon  Harold S. Johnston  Marta Kowalczyk  Ivan Wilson 《Pure and Applied Geophysics》1980,118(1):58-85

The catalytic destruction of stratospheric ozone by the oxides of nitrogen is believed to be an important part of the global ozone balance. The lack of sufficient measurements of NO _x concentrations has impeded efforts to quantify this process. Recent measurements of stratospheric nitrogen dioxide from ground-based stations as well as aircraft and balloons have provided a first approximation to a global distribution of NO₂ vertical columns at sunset. These observed vertical columns have been translated into time-dependent vertical NO₂ profiles by means of a one-dimensional atmospheric photochemical model. Using recent observations of air temperature and ozone along with this information, the independent instantaneous (one second) rates of ozone production from oxygen photolysis P(O₃), of ozone destruction from pure oxygen species (Chapman reactions) L(O _x ), and of ozone destruction by nitrogen oxides L(NO _x ) were estimated over the three-dimensional atmosphere. These quantities are displayed as zonal average contour maps, summed over various latitude zones, summed over various altitude bands, and integrated globally between 15 and 45 km. Although the global summation between 15 and 45 km by no means tells the complete story, these numbers are of some interest, and the relative values are: P(O₃), 100; L(O _x ), 15; L(NO _x ), 45±15. It is to be emphasized that this relative NO _x contribution to the integrated ozone balance is not a measure of the sensitivity of ozone to possible perturbations of stratospheric NO _x ; recent model results must be examined for current estimates of this sensitivity.  相似文献   

Formation,history and energetics of cores in the terrestrial planets   总被引：1，自引：0，他引：1  

Sean C. Solomon 《Physics of the Earth and Planetary Interiors》1979,19(2):168-182

The cores of the terrestrial planets Earth, Moon, Mercury, Venus and Mars differ substantially in size and in history. Though no planet other than the Earth has a conclusively demonstrated core, the probable cores in Mercury and Mars and Earth's core show a decrease in relative core size with solar distance. The Moon does not fit this sequence and Venus may not. Core formation must have been early (prior to ～4 · 10⁹ yr. ago) in the Earth, by virtue of the existence of ancient rock units and ancient paleomagnetism and from UPb partitioning arguments, and in Mercury, because the consequences of core infall would have included extensional tectonic features which are not observed even on Mercury's oldest terrain. If a small core exists in the Moon, still an open question, completion of core formation may be placed several hundred million years after the end of heavy bombardment on tectonic and thermal grounds. Core formation time on Mars is loosely constrained, but may have been substantially later than for the other terrestrial planets. The magnitude and extent of early heating to drive global differentiation appear to have decreased with distance from the sun for at least the smaller bodies Mercury, Moon and Mars.Energy sources to maintain a molten state and to fuel convection and magnetic dynamos in the cores of the terrestrial planets include principally gravitational energy, heat of fusion, and long-lived radioactivity. The gravitational energy of core infall is quantifiable and substantial for all bodies but the Moon, but was likely spent too early in the history of most planets to prove a significant residual heat source to drive a present dynamo. The energy from inner core freezing in the Earth and in Mercury is at best marginally able to match even the conductive heat loss along an outer core adiabat. Radioactive decay in the core offers an attractive but unproven energy source to maintain core convection.  相似文献   

New concepts in ecological risk assessment: where do we go from here?   总被引：10，自引：0，他引：10  

Solomon KR  Sibley P 《Marine pollution bulletin》2002,44(4):279-285

Through the use of safety factors, the use of single-species test data has been adequate for use in protective hazard assessments and criteria setting but, because hazard quotients do not consider the presence of multiple species each with a particular sensitivity or the interactions that can occur between these species in a functioning community, they are ill-suited to environmental risk assessment. Significant functional redundancy occurs in most ecosystems but this is poorly considered in single-species tests conducted under laboratory conditions. A significant advance in effects assessment was the use of the microcosm as a unit within which to test interacting populations of organisms. The microcosm has allowed the measurement of the environmental effect measures such as the NOAEC(community) under laboratory or field conditions and the application of this and other similarly derived measures to ecological risk assessment (ERA). More recently, distributions of single-species laboratory test data have been used for criteria setting and, combined with distributions of exposure concentrations, for risk assessment. Distributions of species sensitivity values have been used in an a priori way for setting environmental quality criteria such as the final acute value (FAV) derived for water quality criteria. Similar distributional approaches have been combined with modeled or measured concentrations to produce estimates of the joint probability of a single species being affected or that a proportion of organisms in a community will be impacted in a posteriori risk assessments. These techniques have not been widely applied for risk assessment of dredged materials, however, with appropriate consideration of bioavailability and spatial and nature of the data these techniques can be applied to soils and sediments.  相似文献   

Sources of radiogenic helium in a clay till aquitard and its use to evaluate the timing of geologic events     

M. Jim Hendry  T.G. Kotzer  D.K. Solomon 《Geochimica et cosmochimica acta》2005,69(2):475-483

Concentrations of dissolved gases (He, Ne, Ar and N₂) were measured in pore waters collected from a Pleistocene (0-80 m depth) and Cretaceous (80-156 m depth) aged, clay-rich, aquitard system using both a conventional copper-tube method and in situ diffusion samplers. Both methods yielded similar results. He data revealed a well-defined increase in concentration with depth, from 1.7 × 10⁻⁸ cm³ He STP g⁻¹ water near the water table (at 2.3 m below ground surface) to 6.9 × 10⁻⁶ cm³ He STP g⁻¹ water at ∼80 m below ground surface (B.G.) The concentration at depth greatly exceeded values for atmospheric solubility at in situ temperatures and could not be attributed to steady-state production from α-decay of U and Th within the aquitard system. Trends in He isotope ratios and concentrations suggest accumulation as a result of both release of residual ⁴He from within the Pleistocene clay-rich till (ca. 87%) and an ascending radiogenic helium flux from underlying Cretaceous-age sediments (ca. 13%). One-dimensional transport modeling of the He data suggests that between 15 ka and 25 ka were required to produce the observed profile. This time frame agrees with studies utilizing isotope tracers (i.e., D/H and ¹⁴C-DIC) to estimate the timing of deposition for the till at this site. Our results demonstrate the utility of using helium, a nonreactive tracer, for delineating hydrogeologic processes in slow permeability geologic strata, and also support the contention that thick clay-rich surficial aquitards can provide long-term containment of contaminants, including hazardous wastes.  相似文献   

Secular cooling of the Earth as a source of intraplate stress     

Sean C. Solomon 《Earth and Planetary Science Letters》1987,83(1-4)

As a result of secular cooling and contraction of the Earth, an increasingly extensional horizontal stress is imposed on the central portions of the plates. While the rate of increase of this stress is small in most situations, it is enhanced for large plates and during any episodes of accelerated global cooling. This source of stress may have contributed to the rifting and breakup of long-lived supercontinental plates.  相似文献   

Global CO2 emissions trading: Early lessons from the U.S. acid rain program     

Barry D. Solomon 《Climatic change》1995,30(1):75-96

The U.S. Environmental Protection Agency is implementing a program of SO₂ emission allowance trading as part of the Acid Rain Program authorized by the Clean Air Act Amendments of 1990. Electric utilities may use allowance trading as part of their compliance strategy to meet SO₂ emission reduction requirements, which begin in 1995. In the interest of a free market in emission credits, some utilities began trading in 1992. A strict but essential requirement for continuous-emissions monitoring was developed to support the trading program. This program is being widely watched and will be evaluated as part of an effort to determine if market concepts can be successfully extended to other environmental issues. One such issue is greenhouse gas emissions and their link with global warming and climate change. This paper focuses on the early lessons learned, issues, and challenges involved in going from a domestic electric utility SO₂ emissions trading program to inter-industry, inter-gas and international as well as national emissions trading and offsets programs. Prominent among these issues are CO₂ allowance allocations, equity, emissions monitoring, enforcement, and cost-effectiveness.Paper presented at the90th Annual Meeting of the Association of American Geographers, San Francisco, April 2, 1994, at the Air & Waste Management Association International Specialty Conference onGlobal Climate Change, Tempe, Arizona, April 8, 1994, and at a Cornell University Center for the Environment seminar on global climate change, April 25, 1994. I thank Michael Grubb, Joe Kruger, Elliot Lieberman, Brian McLean, Renee Rico, Richard Schuler and two anonymous referees for helpful comments on previous drafts of this paper. The views and opinions expressed herein are those of the author alone, and do not necessarily represent the policies of the U.S. Environmental Protection Agency.  相似文献   

Groundwater study using remote sensing and geographic information systems (GIS) in the central highlands of Eritrea   总被引：2，自引：1，他引：2  

Semere Solomon  Friedrich Quiel 《Hydrogeology Journal》2006,14(5):729-741

Remote sensing, evaluation of digital elevation models (DEM), geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Eritrea. Remote sensing data were interpreted to produce lithological and lineament maps. DEM was used for lineament and geomorphologic mapping. Field studies permitted the study of structures and correlated them with lineament interpretations. Hydrogeological setting of springs and wells were investigated in the field, from well logs and pumping test data. All thematic layers were integrated and analysed in a GIS. Results show that groundwater occurrence is controlled by lithology, structures and landforms. Highest yields occur in basaltic rocks and are due to primary and secondary porosities. High yielding wells and springs are often related to large lineaments, lineament intersections and corresponding structural features. In metamorphic and igneous intrusive rocks with rugged landforms, groundwater occurs mainly in drainage channels with valley fill deposits. Zones of very good groundwater potential are characteristic for basaltic layers overlying lateritized crystalline rocks, flat topography with dense lineaments and structurally controlled drainage channels with valley fill deposits. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan.An erratum to this article can be found at  相似文献   

Molecular signature and sources of biochemical recalcitrance of organic C in Amazonian Dark Earths     

Dawit Solomon  Johannes Lehmann  Thorsten Schäfer  James Kinyangi  James Petersen  Jan Skjemstad 《Geochimica et cosmochimica acta》2007,71(9):2285-2298

Amazonian Dark Earths (ADE) are a unique type of soils developed through intense anthropogenic activities that transformed the original soils into Anthrosols throughout the Brazilian Amazon Basin. We conducted a comparative molecular-level investigation of soil organic C (SOC) speciation in ADE (ages between 600 and 8700 years B.P.) and adjacent soils using ultraviolet photo-oxidation coupled with ¹³C cross polarization-magic angle spinning nuclear magnetic resonance (CP-MAS NMR), synchrotron-based Fourier transform infrared-attenuated total reflectance (Sr-FTIR-ATR) and C (1s) near edge X-ray absorption fine structure (NEXAFS) spectroscopy to obtain deeper insights into the structural chemistry and sources of refractory organic C compounds in ADE. Our results show that the functional group chemistry of SOC in ADE was considerably different from adjacent soils. The SOC in ADE was enriched with: (i) aromatic-C structures mostly from H- and C-substituted aryl-C, (ii) O-rich organic C forms from carboxylic-C, aldehyde-C, ketonic-C and quinine-C, and (iii) diverse group of refractory aliphatic-C moieties. The SOC in adjacent soils was predominantly composed of O-alkyl-C and methoxyl-C/N-alkyl-C structures and elements of labile aliphatic-C functionalities. Our study suggests that the inherent molecular structures of organic C due to selective accumulation of highly refractory aryl-C structures seems to be the key factor for the biochemical recalcitrance and stability of SOC in ADE. Anthropogenic enrichment with charred carbonaceous residues from biomass-derived black C (BC) is presumed to be the precursor of these recalcitrant polyaromatic structures. Our results also highlight the complementary role that might be played by organic C compounds composed of O-containing organic C moieties and aliphatic-C structures that persisted for millennia in these anthropic soils as additional or secondary sources of chemical recalcitrance of SOC in ADE. These organic C compounds could be the products of: (i) primary recalcitrant biomolecules from non-BC sources or (ii) secondary processes involving microbial mediated oxidative or extracellular neoformation reactions of SOC from BC and non-BC sources; and stabilized through physical inaccessibility to decomposers due to sorption onto the surface or into porous structures of BC particles, selective preservation or through intermolecular interactions involving clay and BC particles.  相似文献   

The origin and emplacement of the Lajishankou ophiolite complex in the South Qilian belt: evidences from geological mapping     

FU Changlei  YAN Zhen  Solomon BUCHMAN  Jonathan AITCHISON  NIU Manlan 《《地质学报》英文版》2018,92(Z2):9-9

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Quantifying stream-loss recovery in a spring using dual-tracer injections in the Snake Creek drainage,Great Basin National Park,Nevada, USA     

Humphrey  C. Eric  Gardner  Philip M.  Spangler  Lawrence E.  Nelson  Nora C.  Toran  Laura  Solomon  D. Kip 《Hydrogeology Journal》2023,31(4):1051-1066

Simultaneous short-pulse injections of two tracers (sodium bromide [Br^–] and fluorescein dye) were made in a losing reach of Snake Creek in Great Basin National Park, Nevada, USA, to evaluate the quantity of stream loss through permeable carbonates that resurfaces at a spring approximately 10 km down drainage. A revised hydrogeologic cross section for a possible flow path of the infiltrated Snake Creek water is presented, and the results may inform water management in the region. First arrival and peak concentration of the two tracers occurred at 9.5 and 12.7 days after injection, respectively. Fracture transport simulations indicate that Br^– preferentially diffuses into immobile regions of the aquifer, and this diffusive flux is likely responsible for the major differences in the breakthrough curves. When considering the diffusive tracer flux, total apparent Br^– and fluorescein dye recoveries were 16.9–22.1% and 21.7–24.3%, respectively. These findings imply that consideration of diffusive flux and long-term monitoring in fracture-dominated flow may support accurate quantification of tracer recovery. In addition, the apparent power law slopes of the breakthrough tails for both tracers were steeper at early times than have been attributed to heterogeneous advection or channeling in meter-scale tests, but the late-time Br^– power law slope becomes less steep than has been attributed to diffusive exchange. These deviations may reflect fracture transport patterns that occur at larger scales.

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